Gukuraho Hydrogen Sulfide na Mercaptan

Usibye hydrogène sulfide, gaze yameneka peteroli isanzwe irimo urugero rwinshi rwa sulferi kama.Urufunguzo rwo kugabanya ibirimo sulferi ni ugukuraho neza inzoga za sulfure na hydrogen sulfide muri gaze mbisi.Amashanyarazi ya molekulari arashobora gukoreshwa mugutangaza ibice bimwe birimo sulfure.Ihame rya adsorption rikubiyemo ahanini ibintu bibiri:

1- guhitamo imiterere na adsorption.Hariho imiyoboro myinshi ihuriweho nuburyo bwimikorere ya molekile ya elegitoronike, idatanga gusa ubuso bunini bwimbere, ahubwo inagabanya igipimo cya molekile hamwe ninjoro nini yinjira.

2- polar adsorption, bitewe nibiranga lattice ya ion, hejuru ya molekile ya elegitoronike ni polarite nyinshi, bityo ikaba ifite ubushobozi bwo kwinjiza cyane kuri molekile zidahagije, molekile ya polar na molekile byoroshye.Icyuma cya molekulari gikoreshwa cyane cyane mu gukuramo thiol muri gaze gasanzwe.Bitewe na polarite nkeya ya COS, isa na molekulire ya CO₂, hariho irushanwa hagati ya adsorption kumashanyarazi ya molekile imbere ya CO₂.Kugirango byoroshe inzira no kugabanya ishoramari ryibikoresho, molekile ya sikoro ya adsorption sulfate isanzwe ikoreshwa ifatanije no kubura umwuma wa molekile.

Ubushuhe bwa JZ-ZMS3, JZ-ZMS4, JZ-ZMS5 na JZ-ZMS9 icyuma cya molekile ni 0.3nm, 0.4nm, 0.5nm na 0.9nm.Byagaragaye ko icyuma cya JZ-ZMS3 cyoroshye cyane cyakira thiol, icyuma cya JZ-ZMS4 cyinjiza imbaraga nkeya naho icyuma cya JZ-ZMS9 gikurura thiol cyane.Ibisubizo byerekana ko ubushobozi bwa adsorption hamwe na adsorption yiyongera uko aperture yiyongera.